Sunday, April 21, 2013
Phosphaalkyne azide click chemistry
Dalton Trans 2013, Choong et al 3/21/13
1,3-cycloaddition of phosphaalkynes & azides to triazaphosphole:
Uncatalyzed, regioselective, quantitative or near-quantitative yield
Near click chemistry except necessary protection of P(III) from oxidation.
Triazaphospholes as polydentate ligands in metalloorganic, dendrimer, polymer context
Labels:
azide,
click chemistry,
dendrimer,
metalloorganic,
phosphaalkynes,
polymer
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